"Georgia, County Marriages, 1785-1950," database with images, FamilySearch (https://familysearch.org/ark:/61903/1:1:KXVF-Y4R : 30 June 2015), James Brown and Elisebeth A. Highsmith, 30 Dec 1852; citing Marriage, Marion, Georgia, United States, county courthouses, Georgia; FHL microfilm 422,210.
"Georgia Marriages, 1808-1967," database, FamilySearch (https://familysearch.org/ark:/61903/1:1:FWHY-7VH : 24 December 2014), James Brown and Elisebeth A. Highsmith, 30 Dec 1852; citing , Marion, Georgia; FHL microfilm 422,210.
He is not in found in the 1870 Census, but his wife and children are.
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DNA Connections
It may be possible to confirm family relationships with James by comparing test results with other carriers of his Y-chromosome or his mother's mitochondrial DNA.
However, there are no known yDNA or mtDNA test-takers in his direct paternal or maternal line.
It is likely that these autosomal DNA test-takers will share some percentage of DNA with James: