Mostly known from a mention in Crozier. He married Mildred Hawes and they had at least two children, Mildred Charlotte Buckner and Anne Hawes Buckner.
Sources
W.A. Crozier, W.D. Buckner, and H.R. Bayne, The Buckners of Virginia and the Allied Families of Strother and Ashby, Genealogical Association, 1907, p. 131 at Google Books
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DNA Connections
It may be possible to confirm family relationships with William by comparing test results with other carriers of his Y-chromosome or his mother's mitochondrial DNA.
However, there are no known yDNA or mtDNA test-takers in his direct paternal or maternal line.
It is likely that these autosomal DNA test-takers will share some percentage of DNA with William: