Remarried after her first husband Henry was killed in the Civil War at the Battle of Upperville in 1863.
Sources
"United States Census, 1850," database with images, FamilySearch (https://familysearch.org/ark:/61903/1:1:M4BF-LC6 : accessed 17 March 2016), Caroline Carter in household of John Carter, Randolph county, part of, Randolph, North Carolina, United States; citing family 684, NARA microfilm publication M432 (Washington, D.C.: National Archives and Records Administration, n.d.).
"North Carolina Marriages, 1759-1979," database, FamilySearch (https://familysearch.org/ark:/61903/1:1:F823-BTP : accessed 17 March 2016), Caroline Carter in entry for William A. King and Margaret Minor, 13 Feb 1869; citing Davie, North Carolina, reference Pg3 #6; FHL microfilm 572,607.
"North Carolina Marriages, 1759-1979," database, FamilySearch (https://familysearch.org/ark:/61903/1:1:F8YW-HLC : accessed 17 March 2016), Henry Minor and Margaret Ann Carter, 17 Mar 1859; citing Davie,North Carolina, reference ; FHL microfilm 6,330,311.
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DNA Connections
It may be possible to confirm family relationships with Margaret by comparing test results with other carriers of her ancestors' mitochondrial DNA.
However, there are no known mtDNA test-takers in her direct maternal line.
It is likely that these autosomal DNA test-takers will share some percentage of DNA with Margaret: