Per his grave memorial [1] Matthias Corwin married first, in 1782 in Fayette County, Pennsylvania, Patience Hallock, with whom he may have had 9 children (surname Corwin presumably):
Warren County Genealogical Society, editor, Warren County Cemetery Records, 7 (Lebanon, Ohio: Warren County Geneological Society, 1984-1988), 7: 460.
Ohio, Church Records, 1762-2008," database, FamilySearch (https://familysearch.org/ark:/61903/1:1:QGLS-5QWP : 15 October 2019), Mathias Corwin, 4 Sep 1829; citing Death, Ohio, United States, multiple educational, religious, and private organizations.
The Corwin Genealogy (Curwin, Curwen, Corwine) in the United States. Ancestry.com Operations, Inc., Provo, UT, USA 2005
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DNA Connections
It may be possible to confirm family relationships with Matthias by comparing test results with other carriers of his Y-chromosome or his mother's mitochondrial DNA.
However, there are no known yDNA or mtDNA test-takers in his direct paternal or maternal line.
It is likely that these autosomal DNA test-takers will share some percentage of DNA with Matthias: