She was not listed in the 1891 census with the family but did appear in the 1901 census. It is possible she went to live with another family in her younger years.
Sources
1885 Birth: "Ontario Births, 1869-1912," database with images, FamilySearch (https://familysearch.org/ark:/61903/1:1:FMDN-DVD : 16 July 2017), Anna D. Durocher, 06 Mar 1885; citing Birth, Sandwich East Township, Essex, Ontario, Canada, citing Archives of Ontario, Toronto; FHL microfilm 1,845,873.
1891 Census: Age 6 and living with parents in Sandwich East
1901 Census: Age 16. listed as Emma and living with parents and 5 siblings in Essex North
Marriage record
1911 Census: Listed at age 26 and living with husband and son in Windsor, Ontario
1921 Census: Listed at age 35 and living with husband and son at 821 Lanspery in Windsor, Ontario
Gravestone: Buried at St. Alphonsus cemetery in Windsor, Ontario
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DNA Connections
It may be possible to confirm family relationships with Emma by comparing test results with other carriers of her mitochondrial DNA.
However, there are no known mtDNA test-takers in her direct maternal line.
It is likely that these autosomal DNA test-takers will share some percentage of DNA with Emma: