George Gustavus Green was first married to Adaline Melissa Briggs, who died 01 Aug., 1860. He and Adaline had a daughter - Emma (b. 01 Jan 1857).
Sources
Find A Grave Index," database, FamilySearch (https://familysearch.org/pal:/MM9.1.1/QVGM-9G9W : 13 December 2015), George G Green, 1893; Burial, Wausau, Marathon, Wisconsin, United States of America, Pine Grove Cemetery; citing record ID 104085499, Find a Grave, http://www.findagrave.com.
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DNA Connections
It may be possible to confirm family relationships with George by comparing test results with other carriers of his Y-chromosome or his mother's mitochondrial DNA.
However, there are no known yDNA or mtDNA test-takers in his direct paternal or maternal line.
It is likely that these autosomal DNA test-takers will share some percentage of DNA with George: