Daniel is the son of Amasa Killam and Sarah Sanford.
Sources
"Canada, Nova Scotia Marriages, 1864-1918," database with images, FamilySearch (https://www.familysearch.org/ark:/61903/1:1:WHG4-CKN2 : 14 December 2020), Daniel Killam in entry for Robert Killam, 28 Feb 1868; citing Marriage, Granville Ferry, Annapolis Royal, Annapolis, Nova Scotia, Canada, Nova Scotia Archives, Halifax; FHL microfilm 004059097.
Sanford, John Minard. John Sanford Genealogy: President John Sanford of BOSTON MASSACHUSETTS AND PORTSMOUTH, RHODE ISLAND 1605-1695 AND HIS DESCENDANTS WITH MANY ALLIED FAMILIES. Self Compiled and Published (244 Walnut Street, East Aurora, New York). Copyright 1966. p. 124
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DNA Connections
It may be possible to confirm family relationships with Daniel by comparing test results with other carriers of his Y-chromosome or his mother's mitochondrial DNA.
However, there are no known yDNA or mtDNA test-takers in his direct paternal or maternal line.
It is likely that these autosomal DNA test-takers will share some percentage of DNA with Daniel: