Valentine was born in 1774. Valentine Martin ... He passed away in 1855.
Sources
Census Records 1850
"United States Census, 1850," database with images, FamilySearch (Index Link : accessed 20 January 2016), Valentine Martin in household of James Castles, Newton county, Newton, Mississippi, United States; citing family 70, NARA microfilm publication M432 (Washington, D.C.: National Archives and Records Administration, n.d.).
"United States Census, 1850," database with images, FamilySearch (Index Link : accessed 21 January 2016), Valentine Martin, Lauderdale county, Lauderdale, Mississippi, United States; citing family 925, NARA microfilm publication M432 (Washington, D.C.: National Archives and Records Administration, n.d.).
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How certain are you of his spouse's name being Nancy?