"Scotland Births and Baptisms, 1564-1950," database, FamilySearch (https://familysearch.org/ark:/61903/1:1:XB83-M3D : 8 December 2014), James Mitchell in entry for Ann Mitchell, 04 Dec 1842; citing , reference ; FHL microfilm 993,405, 993,408, 993,403, 993,408.
"Scotland Marriages, 1561-1910," database, FamilySearch (https://familysearch.org/ark:/61903/1:1:XTVD-D27 : 8 December 2014), Andrew Rattray and Ann Mitchell, 29 Mar 1861; citing Dundee,Angus,Scotland, reference ; FHL microfilm 6,035,516.
NZ DIA death registration 1922/6979: Ann Rattray (born 1842) passed away aged 80Y on 21 July 1922
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DNA Connections
It may be possible to confirm family relationships with Ann by comparing test results with other carriers of her mitochondrial DNA.
However, there are no known mtDNA test-takers in her direct maternal line.
It is likely that these autosomal DNA test-takers will share some percentage of DNA with Ann: