James Potter and family lived in Crawford County GA before moving to Alabama before the 1840 census. It is very likely they were in Hancock County before May 1823 when he purchased land in Crawford County, GA.
Sources
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DNA Connections
It may be possible to confirm family relationships with James by comparing test results with other carriers of his Y-chromosome or his mother's mitochondrial DNA.
However, there are no known yDNA or mtDNA test-takers in his direct paternal or maternal line.
It is likely that these autosomal DNA test-takers will share some percentage of DNA with James: