From all the sources obtained, it shows that he was married to a Nancy Berry, rather than Nancy Burks. Nancy Burks was from Alabama and died in Arkansas, no records of her in Maine. Cindy Williams Lesure
Family Tree of Green and Williams www.familytreeguide
"United States Census, 1840," database with images, FamilySearch (https://familysearch.org/ark:/61903/1:1:XHYS-NQ5 : 24 August 2015), Zachariah Williams, Embden, Somerset, Maine, United States; citing p. 181, NARA microfilm publication M704, (Washington D.C.: National Archives and Records Administration, n.d.), roll 151; FHL microfilm 9,708.
"United States Census, 1850," database with images, FamilySearch (https://familysearch.org/ark:/61903/1:1:M6VW-5J9 : 12 April 2016), Zachariah Williams, Embden, Somerset, Maine, United States; citing family 37, NARA microfilm publication M432 (Washington, D.C.: National Archives and Records Administration, n.d.).
"United States Census, 1870," database with images, FamilySearch (https://familysearch.org/ark:/61903/1:1:M6D1-2PL : 12 April 2016), Zacheriah Williams, Maine, United States; citing p. 8, family 64, NARA microfilm publication M593 (Washington D.C.: National Archives and Records Administration, n.d.); FHL microfilm 552,057.
"Maine Vital Records, 1670-1921," database with images, FamilySearch (https://familysearch.org/ark:/61903/1:1:KC6Q-89Y : 27 December 2014), Zechariah Williams, Death 20 Dec 1898; citing Division of Vital Statistics, State Board of Health, Augusta; FHL microfilm 10,063.
"Maine, Faylene Hutton Cemetery Collection, ca. 1780-1990," database with images, FamilySearch (https://familysearch.org/ark:/61903/1:1:QKM1-7875 : 16 April 2015), Zachariah Williams, 1898; citing Burial, North Anson, Somerset, Maine, United States, Maine State Library, Augusta; FHL microfilm 1,787,636.
WIkiTree profile created by William Ramage on August 29, 2012.
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DNA Connections
It may be possible to confirm family relationships with Zachariah by comparing test results with other carriers of his Y-chromosome or his mother's mitochondrial DNA.
However, there are no known yDNA or mtDNA test-takers in his direct paternal or maternal line.
It is likely that these autosomal DNA test-takers will share some percentage of DNA with Zachariah: