Surname should be Walker. Father was born James Walker, and later unofficially changed his name to James Walker Williams to avoid a Bigamy charge.
Sources
Death Certificate NSW BDM 1953/023643
Australian, New South Wales, Births Deaths Marriages, Marriage Registration 10461/1916, Groom = Edward H Williams, Bride = Edith Davidson, Registered at Bellingen NSW.
"INSULTED A RELATIVE." Newcastle Morning Herald and Miners' Advocate (NSW : 1876 - 1954) 10 January 1931: 12. Web. 17 Oct 2017 <http://nla.gov.au/nla.news-article137689843>.
1953 'IN the matter of the estates of the undermentioned deceased', Government Gazette of the State of New South Wales (Sydney, NSW : 1901 - 2001), 20 November, p. 3876. , viewed 17 Oct 2017, http://nla.gov.au/nla.news-article220298490
"Find A Grave Index," database, FamilySearch (https://familysearch.org/ark:/61903/1:1:Q2WY-3YN6 : 19 September 2016), Edward H Williams, 1953; Burial, Sutherland, Sutherland Shire, New South Wales, Australia, Woronora Cemetery and Crematorium; citing record ID 167522624, Find a Grave, http://www.findagrave.com.
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DNA Connections
It may be possible to confirm family relationships with Edward by comparing test results with other carriers of his Y-chromosome or his mother's mitochondrial DNA.
However, there are no known yDNA or mtDNA test-takers in his direct paternal or maternal line.
It is likely that these autosomal DNA test-takers will share some percentage of DNA with Edward: