For Jonathan Webb 1675-1744 mentioned in this query, his profile is in WT; his list of descendants does not include William Riley Webb
There is no William Riley Webb 1818 - 1884 indexed on WT; there is a William Riley Webb born about 1818 and died 1874 of Jackson, Tennessee; he has no ancestors on his profile
Insofar as the contents of WT and its profiles it does not appear that the two men connect