Hi Karen There are clues in your photos based on poses, clothing, hair styles, and furniture or other objects in the photos. Often there are people attached to local history museums, art museums, and local universities who might be able to help you at least sort them into time frames and then you might be able to match them to people in your trees. I was able to do that with a photo we knew was family but no living family knew exactly who the people in the image were.
Also some might be friends, neighbors, or old suitors for your family.
Are there family resemblances? We found a portrait of my husband's great great grandmother at a younger age and his sister is the spitting image of her.so sometimes there are strong physical characteristics that come down through the ages. Particularly look at ears and noses. Eye shape and face shape as they are often inherited.