As Paula noted, it will be useful to explore alternative spellings of places; and I have found Maine census-takers spelling my ancestors names Wiley, Wilie, and Wylie. The -scot suffix was used in Abenaki place names referring to large rivers, or possibly the estuaries at the mouths of such rivers. The two best known are the Penobscot near Bangor, and the Presumpscot near Portland. There may have been others whose Abenaki names were not preserved by Europeans.
Records of European genealogists seem very sparse concerning the European fishermen living along the Maine coast through the 16th and 17th centuries. The French and Indian Wars destroyed most records of the Maine coast during the first century of your Willey's North American residency. My Wylie ancestors were living near the Kennebec River estuary and appear to have arrived from Ireland in the 1740s during the famine of the great frost which, although today less remembered than the great famine a century later, actually killed a larger percentage or the Irish population,