What information are you looking for? His baptism is on Scotlandspeople. Father William Shand, Mother Isabelle B. You can access the index for free and view the record image if you buy credits.
This could be him (pasted below) and here is the same record record on the archives of Canada Website (online census records): http://data2.collectionscanada.gc.ca/1861/jpg/4108794_00336.jpg
"Québec, recensement, 1861," database, FamilySearch(https://familysearch.org/ark:/61903/1:1:MMWQ-G7H : 9 March 2018), Joseph Shand, St-Thomas, Missisquoi, Quebec, Canada; citing line number 12, p. 381; Library and Archives Canada film number C-1297, Archives Publiques, Ottawa (Board of Registration and Statistics. Public Archives, Ottawa); FHL microfilm 517,397.