Assuming Catherine was born about 1835, she cannot be the Catherine Legge who married Alexander Russell 25 Nov 1838 in Chester, NS. I cannot find other sources that fit our Catherine in FamilySearch. Whitten-1 05:36, 23 September 2017 (EDT)
"LEGGE","Cath","B","1835-10-31","1835-11-13","SJAL","George Michael & Maria E Vienot",
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DNA Connections
It may be possible to confirm family relationships with Catherine by comparing test results with other carriers of her ancestors' mitochondrial DNA.
However, there are no known mtDNA test-takers in her direct maternal line.
It is likely that these autosomal DNA test-takers will share some percentage of DNA with Catherine: