Apparently James married (1) Mary (Reitlehover) Ballentine (abt. 1765 - abt. 1811) and (2) Anna Rosanna (Reitlehover) Ballentine (1786 - 1874). So he must still have been married to Mary in 1794, when his son James William Ballentine Jr. (1794 - 1856) was born and in 1804, when his daughter Elizabeth (Ballentine) Frick (abt. 1804 - 1854) was born. Also, Anna Rosanna was too young to be the mother of James William Jr. (she was 8 years old at the time of his birth). And according to James William Jr.'s Find A Grave entry, Mary was his mother. So both children were disconnected from Anna Rosanna and connected to Mary as their mother.
Sources
↑ 1790 United States Federal Census; The National Archives in Washington, DC; Washington, DC; First Census of the United States, 1790.; Year: 1790; Census Place: Orangeburg, South Carolina; Series: M637; Roll: 11; Page: 398; Family History Library Film: 0568151
↑ Heads of Families at the First Census of the United States Taken in the Year 1790: South Carolina
↑ Find A Grave: Memorial #114561622 for William Ballentine, Jr., b: 03 Dec 1773 South Carolina, USA; d: 02 Jul 1842 Chapin, Lexington County, South Carolina, USA; buried: Ballentine Plantation Graves, Chapin, Lexington County, South Carolina, USA
1850 USA Census of Lexington, Lexington County, South Carolina; on ancestry.com citing NARA# M432_855; image#349; p374B; family#518; which included ...
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DNA Connections
It may be possible to confirm family relationships with James by comparing test results with other carriers of his Y-chromosome or his mother's mitochondrial DNA.
However, there are no known yDNA or mtDNA test-takers in his direct paternal or maternal line.
It is likely that these autosomal DNA test-takers will share some percentage of DNA with James: