Neil was born about 1794.
Married in 1820 Spouse is Mary b.1796 in Scotland
Sources
"Scotland Marriages, 1561-1910," database, FamilySearch (https://familysearch.org/ark:/61903/1:1:XTKJ-9HZ : 8 December 2014), Neil Blue and Mary Smith, 19 Feb 1820; citing South Knapdale,Argyll,Scotland, index based upon data collected by the Genealogical Society of Utah, Salt Lake City; FHL microfilm 1,041,077.
"Canada, recensement du Bas-Canada, 1842," database with images, FamilySearch (https://familysearch.org/ark:/61903/1:1:X73Z-29P : 18 November 2014), Neil Blue, Métis, Rimouski, Quebec, Canada; citing p. 3518, volume MG 31 C1, MG 31 C1; Library and Archives Canada microfilm number C-733, Public Archives, Ottawa, Ontario; FHL microfilm 2,443,973.
"Canada Census, 1851," database, FamilySearch (https://familysearch.org/ark:/61903/1:1:MWRJ-CL8 : 3 August 2016), Neal Blue, Métis, Rimouski County, Canada East (Quebec), Canada; citing p. 3, line 19; Library and Archives Canada film number C_1136, Public Archives, Ontario.
Likely birth record: "Scotland Births and Baptisms, 1564-1950," database, FamilySearch (https://familysearch.org/ark:/61903/1:1:XY8H-3Z1 : 2 January 2015), Neil Blue in entry for Neil Blue, 23 Mar 1798; citing GLASSARY,ARGYLL,SCOTLAND, reference , index based upon data collected by the Genealogical Society of Utah, Salt Lake City; FHL microfilm 1,041,007.
Booklet "Blue Family of Metis" 20 Jan 2019 by Ronald L Blue
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DNA Connections
It may be possible to confirm family relationships with Neil by comparing test results with other carriers of his Y-chromosome or his mother's mitochondrial DNA.
However, there are no known yDNA or mtDNA test-takers in his direct paternal or maternal line.
It is likely that these autosomal DNA test-takers will share some percentage of DNA with Neil: