There may be additional older children not listed in the 1841 census.
Sources
"England Marriages, 1538–1973 ," database, FamilySearch (https://familysearch.org/ark:/61903/1:1:N288-GJ4 : 10 February 2018), John Miles and Charlotte Chapman, 04 Sep 1819; citing Aspeden,Hertford,England, reference , index based upon data collected by the Genealogical Society of Utah, Salt Lake City; FHL microfilm 991,329.
"England and Wales Census, 1841," database with images, FamilySearch (https://familysearch.org/ark:/61903/1:1:MQYX-C7L : 24 May 2019), Charlotte Miles in household of John Chapman, Aspenden, Hertfordshire, England, United Kingdom; from "1841 England, Scotland and Wales census," database and images, findmypast (http://www.findmypast.com : n.d.); citing PRO HO 107, The National Archives, Kew, Surrey.
1861 England Census. Class: RG 9; Piece: 811; Folio: 86; Page: 5; GSU roll: 542704. Original data: Census Returns of England and Wales, 1861. Kew, Surrey, England: The National Archives of the UK (TNA): Public Record Office (PRO), 1861. Data imaged from The National Archives, London, England. Image
1871 England Census. The National Archives; Kew, London, England; Class: RG10; Piece: 1358; Folio: 2; Page: 11; GSU roll: 828294. Original data: Census Returns of England and Wales, 1871. Kew, Surrey, England: The National Archives of the UK (TNA): Public Record Office (PRO), 1871. Data imaged from the National Archives, London, England. Image
"England and Wales Death Registration Index 1837-2007," database, FamilySearch (https://familysearch.org/ark:/61903/1:1:2JJN-T3B : 31 December 2014), Charlotte Miles, 1874; from "England & Wales Deaths, 1837-2006," database, findmypast (http://www.findmypast.com : 2012); citing Death, Royston, Hertfordshire, England, General Register Office, Southport, England.
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DNA Connections
It may be possible to confirm family relationships with Charlotte by comparing test results with other carriers of her mitochondrial DNA.
However, there are no known mtDNA test-takers in her direct maternal line.
It is likely that these autosomal DNA test-takers will share some percentage of DNA with Charlotte: