Massachusetts Births and Christenings shows her as "Polly Darling", b, 12 Aug 1801 in Spencer, MA.
Death
Massachusetts Deaths and Burials:
Name Mary Darling
Gender Female
Death Date 20 May 1879
Age 78
Birth Date 1801
Father's Name Zenas Darling
Mother's Name Dorothy
Sources
"Massachusetts Births and Christenings, 1639-1915," database, FamilySearch (https://familysearch.org/ark:/61903/1:1:FCKJ-PMP : 10 February 2018), Zenas Darling in entry for Polly Darling, 12 Aug 1801; citing SPENCER,WORCESTER,MASSACHUSETTS, ; FHL microfilm 0874027 IT 2.
"Massachusetts Deaths and Burials, 1795-1910," database, FamilySearch (https://familysearch.org/ark:/61903/1:1:FHFY-9XT : 10 February 2018), Zenas Darling in entry for Mary Darling, 20 May 1879; citing , reference Item 7 p 133; FHL microfilm 2,030,960.
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DNA Connections
It may be possible to confirm family relationships with Mary by comparing test results with other carriers of her ancestors' mitochondrial DNA.
However, there are no known mtDNA test-takers in her direct maternal line.
It is likely that these autosomal DNA test-takers will share some percentage of DNA with Mary: