Elizabeth had seven siblings. This family lived at Mill Creek, Jackson Co. WV in the 1870 census.
Sources
"United States Census, 1850," database with images, FamilySearch (https://familysearch.org/ark:/61903/1:1:M8DK-X14 : 12 April 2016), Robert Duffield in household of Andrew Duffield, Pocahontas county, part of, Pocahontas, Virginia, United States; citing family 142, NARA microfilm publication M432 (Washington, D.C.: National Archives and Records Administration, n.d.).
Source: 1870, 1880, 1890 US census, Jackson Co. WV.
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DNA Connections
It may be possible to confirm family relationships with Robert by comparing test results with other carriers of his Y-chromosome or his mother's mitochondrial DNA.
However, there are no known yDNA or mtDNA test-takers in his direct paternal or maternal line.
It is likely that these autosomal DNA test-takers will share some percentage of DNA with Robert: