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DNA Connections
It may be possible to confirm family relationships with Mary by comparing test results with other carriers of her mitochondrial DNA.
However, there are no known mtDNA test-takers in her direct maternal line.
It is likely that these autosomal DNA test-takers will share some percentage of DNA with Mary:
Despite what you may have found on FamilySearch, Mary Freeman (married to Joseph Whitney, died 24 July 1864, buried in Dolloff Road Cemetery, Standish, Maine) was born on 24 Dec 1776, not 1778, according to her gravestone inscription. Please see photo on Findagrave.com link listed under Sources.