Valentine was born about 1822. Valentine Hain ... He passed away in 1896.
"United States Census, 1850," database with images, FamilySearch (https://familysearch.org/ark:/61903/1:1:MH57-5BC : 9 November 2014), Valentine Hains in household of Michael Hains, Pike county, Pike, Alabama, United States; citing family 1077, NARA microfilm publication M432 (Washington, D.C.: National Archives and Records Administration, n.d.).
It may be possible to confirm family relationships with Valentine by comparing test results with other carriers of his Y-chromosome or his mother's mitochondrial DNA.
However, there are no known yDNA or mtDNA test-takers in his direct paternal or maternal line.
It is likely that these autosomal DNA test-takers will share DNA with Valentine: