"United States Census, 1900," database with images, FamilySearch (https://familysearch.org/ark:/61903/1:1:M9ZS-P64 : accessed 1 October 2018), Lydia Hatfield in household of Lewis Hatfield, Stafford district, Mingo, West Virginia, United States; citing enumeration district (ED) 92, sheet 17B, family 296, NARA microfilm publication T623 (Washington, D.C.: National Archives and Records Administration, 1972.); FHL microfilm 1,241,766.
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DNA Connections
It may be possible to confirm family relationships with Valentine by comparing test results with other carriers of his ancestors' Y-chromosome or mitochondrial DNA.
Y-chromosome DNA test-takers in his direct paternal line on WikiTree: