Charlotte was the daughter of Samuel and Ann Hawes. She married first Richard Henry Buckner and then after his death his cousin William Aylette Buckner.
Sources
W.A. Crozier, W.D. Buckner, and H.R. Bayne, The Buckners of Virginia and the Allied Families of Strother and Ashby, Genealogical Association, 1907, p. 130 at Google Books
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DNA Connections
It may be possible to confirm family relationships with Charlotte by comparing test results with other carriers of her mitochondrial DNA.
However, there are no known mtDNA test-takers in her direct maternal line.
It is likely that these autosomal DNA test-takers will share some percentage of DNA with Charlotte: