According to "The Head Family" by John Harris Watts, 1963, William Head was a victim of the Indian Massacre on March 22, 1622, at Powle Brook, Virginia, and is the earliest known Head settler of the new world.
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It may be possible to confirm family relationships with William by comparing test results with other carriers of his Y-chromosome or his mother's mitochondrial DNA.
Y-chromosome DNA test-takers in his direct paternal line on WikiTree: