Sylvia was born about 1802. She passed away about 1874.
Sources
"United States Census, 1850," database with images, FamilySearch (https://familysearch.org/ark:/61903/1:1:MCY4-8KC : 12 April 2016), Sylvia Webb in household of John F Webb, Evans, Erie, New York, United States; citing family 399, NARA microfilm publication M432 (Washington, D.C.: National Archives and Records Administration, n.d.).
Find A Grave, database and images (https://www.findagrave.com : accessed 21 August 2019), memorial page for Sylvia Hoyt Webb (28 Jul 1802–21 Sep 1874), Find A Grave Memorial no. 19122150, citing Jerusalem Corners Cemetery, Jerusalem Corners, Erie County, New York, USA ; Maintained by Michael Harrington (contributor 46760007) . https://www.findagrave.com/memorial/19122150/sylvia-webb
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DNA Connections
It may be possible to confirm family relationships with Sylvia by comparing test results with other carriers of her mitochondrial DNA.
However, there are no known mtDNA test-takers in her direct maternal line.
It is likely that these autosomal DNA test-takers will share some percentage of DNA with Sylvia: