Thomas was born in 1676 in Llandaff Court. He was the son of Colonel Edward Matthews. His maternal grandfather was Thomas Armstrong MP (1633-1684).
He joined the navy in 1690.
He married Henrietta Burgess of Antigua in 1705. They had a son Thomas who became a Major in the army.
Henrietta died about 1740 and Thomas remarried to Milicent Powell in 1745.
He passed away in 1751.
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