She was originally from Verchnaya Dobrinka, also known as Dreispitz. I checked for her parents in the 1767 and 1798 censuses, and there were no Munders in Dreispitz. There were no Munders in any Volga German village in 1798. It is most likely that her last name at birth was misspelled.
Sources
The 1775 and 1798 Census of the German Colony on the Volga, Lesnoy Karamysh, also known as Grimm; Published by the American Historical Society of Germans from Russia, Lincoln, NE, USA; Published 1995; family #23 in the 1798 census, Maria Eva Munder Kimmel, age 22, from Dreispitz.
1834 Census of Grimm in the District of Saratov, Russia, dated 2 February 1835; Translated by Brent Mai, Concordia University, Portland, Oregon; Published by Dynasty Publishing, Beaverton, OR, USA; Published 2011; page 17, family #54, line 556, Eva Kimmel, age 53.
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DNA Connections
It may be possible to confirm family relationships with Eva by comparing test results with other carriers of her mitochondrial DNA.
However, there are no known mtDNA test-takers in her direct maternal line.
It is likely that these autosomal DNA test-takers will share some percentage of DNA with Eva: