Caroline was baptized 15 Dec 1826, at least 4 of these siblings were baptized on the same day.
Sources
Captain John Hatfield: A Genealogy of the Descendants of Captain John Hatfield, Loyalist by Abraham Hatfield, pg 15
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DNA Connections
It may be possible to confirm family relationships with Caroline by comparing test results with other carriers of her ancestors' mitochondrial DNA.
However, there are no known mtDNA test-takers in her direct maternal line.
It is likely that these autosomal DNA test-takers will share some percentage of DNA with Caroline: