I've picked this ancestor up as a result of 11 DNA matches to Opie's and my own paper trail with the James family.
England, Cornwall Parish Registers
Name Henry James
Event Type Marriage
Event Date Feb 1808
Event Place St Agnes, Cornwall, England, United Kingdom
Marital Status Single
Spouse's Name Jane Opie
Spouse's Marital Status Single
Jane James in the 1851 England Census
Age: 60
Estimated Birth Year: abt 1791
Relation: Head
Where born: St Agnes, Cornwall, England
Civil Parish: St Agnes
Ecclesiastical parish: Mount Hawke
County/Island: Cornwall
Country: England
Registration District: Truro
Sub-registration District: Probus
Household Members:
Name Age
Jane James 60 widow
Wm James 26
Thomas James 22
Hariott James 20
Lavinia Harpor 20 visitor
Sources
ancestrydna.com
"England, Cornwall Parish Registers, 1538-2010," database with images, FamilySearch (https://familysearch.org/ark:/61903/1:1:QGLK-YHVB : 2 February 2018), Henry James and Jane Opie, Feb 1808; citing Marriage, St Agnes, Cornwall, England, United Kingdom, Cornwall Records Office, Truro.
1841 England Census
1851 England Census
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DNA Connections
It may be possible to confirm family relationships with Jane by comparing test results with other carriers of her mitochondrial DNA.
However, there are no known mtDNA test-takers in her direct maternal line.
It is likely that these autosomal DNA test-takers will share some percentage of DNA with Jane: