Mary Catherine Powell was born about 1768 in Somerset, Pennsylvania. She passed away about 1821 in Botetourt, Virginia.
Does anyone that is a DNA match have any to the family name Powell? It is highly suspect this is the correct wife as Mary Powell's husband Jacob died in 1813 in Maryland.
Sources
Early American Marriages: Virginia to 1850
Maryland Revolutionary War Records
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DNA Connections
It may be possible to confirm family relationships with Mary by comparing test results with other carriers of her mitochondrial DNA.
However, there are no known mtDNA test-takers in her direct maternal line.
It is likely that these autosomal DNA test-takers will share some percentage of DNA with Mary: