No marriage registration in England/Wales for this couple, 1841-1847.
Sources
"Scotland Births and Baptisms, 1564-1950," database, FamilySearch (https://familysearch.org/ark:/61903/1:1:X154-C8X : 10 February 2018), Daniel Radcliffe in entry for Anne Radcliffe, 17 Jun 1821; citing , AVONDALE, LANARK, SCOTLAND, reference , index based upon data collected by the Genealogical Society of Utah, Salt Lake City; FHL microfilm 1,041,474.
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DNA Connections
It may be possible to confirm family relationships with Annie by comparing test results with other carriers of her mitochondrial DNA.
However, there are no known mtDNA test-takers in her direct maternal line.
It is likely that these autosomal DNA test-takers will share some percentage of DNA with Annie: