Johann Adam (1790-1861): Married twice: Magdalena Kirschenmann (1796-1836), 7 children; Catharina Reuther (1818-unknown), 8 children.
Wilhelm Adam (1794-1868): Married twice: Katharina Gelzler (1796-1826), 4 children; Anna Margaretha Kapp (1810-1851), 12 children.
In 1807, at the age of 57, Sibilla and her family immigrated from Heuchelheim to the village of Freudental in the the Glückstal district of the Odessa area and Black Sea region of South Russia. The family then relocated to the nearby village of Neudorf when it was established in 1809.
Sometime before 1811, around the age of 60, Sibilla passed away in Neudorf. 
↑ Ancestry.com. Rhineland, Bavaria, Palatinate and Rhineland-Palatinate, Germany, Lutheran Baptisms, Marriages, and Burials, 1556-1973 [database on-line]. Lehi, UT, USA: Ancestry.com Operations, Inc., 2016. Transcript: Name: Sibilla Schwarz; Record Type: Taufe (Baptism); Birth Date: 31 Jul 1750; Baptism Date: 2 Aug 1750; Baptism Place: Heuchelheim, Bayern (Bavaria), Preußen; Father: Henrich Schwarz; Mother: Kath Elisabetha Schwarz; City or District: Bergzabern u Heuchelheim; Author: Evangelisch-Reformierte Kirche Heuchelheim (BA. Bergzabern)
↑ 3.03.13.2Glückstal Colonies Points of Origin, Margaret Freeman and Gwen Pritzkau, Edited & Annotated by Thomas A. Stangl (2008); Gluckstalers DVD; Glückstal Colonies Research Association, Page 181, A.Hieb.
Transcript: Johann Adam Hieb (*ca 1746 Leinsweiler/Landau-Pf, son of Johannes Hieb and Maria Catharina; +ca 1826 Neudorf) of 1816 NRL:28, father of the Hieb families, moved to landless 1816 NRL:104 with his son, Johann Adam Hieb Jr (+8.1.1861 N, *9.12.1792 Heuchelheim; m1 ca 1816 to Magdalena Kirschenmann [1816 NRL:32, age 19; +18.9.1836, *ca 1796 Durrweiler-Wü]; m2 on 18.1.1837 to Katharina Reuther [1858 age 40, *ca 1818, daughter of Friedrich Jacob Reuter & Katharina Ritter of 1816 NRL:3 – see Reuter, Joh. Friedr.]; in 1858 NRL:218).
Johann Adam Hieb Sr’s wife was Sibilla Schwartz (*31.7.1750 Heuchelheim, daughter of Heinrich Schwartz and Katharina Elisabetha nee ?); they married on 23.4.1771 in Heuchelheim-Pf. It is assumed that Sibilla may have emigrated with the Hieb family, but died before 1811. Based on a letter from Russia to Elsass, dated in 1808, written by Johann Adam Hieb to his brother-in-law, Georg Koch, in Selz-El (Joseph Height, Homesteaders on the Steppe, p. 50), the Hieb family, after arriving in 1807, was initially placed in the colony of Freudental (12 miles west of Odessa; 9 miles east of Moldovia). The Hieb family relocated to Neudorf when it was established in 1809.
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It may be possible to confirm family relationships with Sibilla by comparing test results with other carriers of her mitochondrial DNA.
However, there are no known mtDNA test-takers in her direct maternal line.
It is likely that these autosomal DNA test-takers will share some percentage of DNA with Sibilla: