Catherine was born in 1827 and passed away in 1877. She was the daughter of Jacob Smith and Sarah Jones.
Sources
"United States Census, 1850," database with images, FamilySearch (https://familysearch.org/ark:/61903/1:1:M4Z3-9KD : 12 April 2016), Catherine Smith in household of Jacob Smith, Hartley, Union, Pennsylvania, United States; citing family 77, NARA microfilm publication M432 (Washington, D.C.: National Archives and Records Administration, n.d.).
"United States Census, 1870," database with images, FamilySearch (https://familysearch.org/ark:/61903/1:1:MZ2J-QL7 : 12 April 2016), Catherine Catherman in household of Elias Catherman, Pennsylvania, United States; citing p. 23, family 176, NARA microfilm publication M593 (Washington D.C.: National Archives and Records Administration, n.d.); FHL microfilm 552,957.
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DNA Connections
It may be possible to confirm family relationships with Catherine by comparing test results with other carriers of her ancestors' mitochondrial DNA.
However, there are no known mtDNA test-takers in her direct maternal line.
It is likely that these autosomal DNA test-takers will share some percentage of DNA with Catherine: