"England and Wales Census, 1861," database with images, FamilySearch (https://familysearch.org/pal:/MM9.1.1/Q2ML-PBBY : 10 December 2017), Eliza Smith in household of John Smith, Bromley, London, Middlesex, England; from "1861 England, Scotland and Wales census," database and images, findmypast (http://www.findmypast.com : n.d.); citing PRO RG 9, The National Archives, Kew, Surrey.
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It may be possible to confirm family relationships with Ann by comparing test results with other carriers of her ancestors' mitochondrial DNA.
However, there are no known mtDNA test-takers in her direct maternal line.
It is likely that these autosomal DNA test-takers will share DNA with Ann: