Joseph married as her first husband, Hannah Strange, daughter of Lot and Hannah (Hathaway) Strange, in 1755 at Freetown, Bristol, Massachusetts - parents of Abigail, William and Joseph II Valentine
"Appt. of Hannah Valentine of Freetown, widow, to be Admx. of estate of Joseph Valentine of Freetown, deceased, intestate, dated 3 Nov 1761"
After his death Hannah married John Nichols on 4 Feb 1762 at Freetown, Bristol, Massachusetts
Sources
Massachusetts Town and Vital Records, 1620-1988
Massachusetts Compiled Marriages, 1695-1910
"Abstracts of Bristol County, Massachusetts Probate Records, 1687-1745", by H. L. Peter Rounds, (Baltimore, Maryland, Genealogical Pub. Co., Inc, 1987) Vol 7, p 533
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DNA Connections
It may be possible to confirm family relationships with Joseph by comparing test results with other carriers of his Y-chromosome or his mother's mitochondrial DNA.
However, there are no known yDNA or mtDNA test-takers in his direct paternal or maternal line.
It is likely that these autosomal DNA test-takers will share some percentage of DNA with Joseph: