Mary Walker and some siblings were baptized at Brinklow, Warwick, England.  Morley Thomas. MEADOWS: a Genealogy of a Pioneer Family in Western Ontario. 2000.
" Richard Wilkins of this Parish, Bachelor and Mary Walker, Spinster of the same parish, married in this Church by Banns, this fifteenth Day of October in the year of our Lord One Thousand Seven Hundred and Seventy Five."  Both Richard and Mary signed with their mark.
Mary Walker Wilkins was buried on 28 Nov 1822 in Brinklow, Warwick, England. 
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It may be possible to confirm family relationships with Mary by comparing test results with other carriers of her mitochondrial DNA.
However, there are no known mtDNA test-takers in her direct maternal line.
It is likely that these autosomal DNA test-takers will share some percentage of DNA with Mary: