Anne was born about 1823. She passed away about 1887.
Sources
"England Births and Christenings, 1538-1975", database, FamilySearch (https://www.familysearch.org/ark:/61903/1:1:NLJN-3XZ: 4 February 2023), Ann in entry for Emily Smith, 1843. Father's Name: William Smith and Mother's Name: Ann.
Marriage to William Henry Smith. "England, Devon and Cornwall Marriages, 1660-1912," database with images, FamilySearch, (https://familysearch.org/ark:/61903/1:1:QGY9-LTP6: 24 April 2019), Ann Ley, Spinster in entry for William Henry Smith, Bachelor, 9 May 1839; citing Marriage, Withycombe Raleigh with Exmouth All Saints, Devon, England, United Kingdom, the Devon Record Office, Exeter. Name William Henry Smith, Bachelor; Residence Place Withycombe Raleigh; Spouse's Name Ann Ley, Spinster; Spouse's Residence Place Exeter St Lawrence; Event Type Marriage Event Date 9 May 1839.
Marriage: "Devon, England, Church of England Marriages and Banns, 1754-1920", Indexes created from Anglican Parish Registers held at South West Heritage Trust; Taunton, Somerset, England, Ancestry Record 62287 #599586 (accessed 10 June 2023) William Henry Brown Hill (21) marriage to Ann Smith in May 1843 in Exeter, St Edmund, Devon, England.
"England and Wales Census, 1851," database with images, FamilySearch (https://familysearch.org/ark:/61903/1:1:SGNB-Z5Y: 9 November 2019), Ann Hill in household of William H B Hill, St Martin, Devon, England; citing St Martin, Devon, England, p. 41, from "1851 England, Scotland and Wales census," database and images, findmypast (http://www.findmypast.com: n.d.); citing PRO HO 107, The National Archives of the UK, Kew, Surrey.
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DNA Connections
It may be possible to confirm family relationships with Anne by comparing test results with other carriers of her mitochondrial DNA.
However, there are no known mtDNA test-takers in her direct maternal line.
It is likely that these autosomal DNA test-takers will share some percentage of DNA with Anne: