Knowing his spouse's name through his childrens' birth records I can identify his wedding record (there are three persons by the name "Martin Wolff" around at that critical time in history).
The record gives his title as "Honestus".
At the wedding in 1803 his father, Peter Wolff, is already deceased. The bride's father, Mathias Hey, is also deceased. That may account for the number of bestmen:
The names are:
Johann Peter Theissen
Mathias Lieperz
Anton Theissen
Sources
Martin Wolff is noted at his son Peter Josef's wedding on page 150 as documented by Westdeutsche Gesellschaft für Familienkunde: Jonas, Klaus: St. Martinus Schmidtheim rk 1806-1890 [1].
His wedding record gives his date of birth and his parents' names as documented by Westdeutsche Gesellschaft für Familienkunde: Jonas, Klaus: St. Martinus Schmidtheim rk 1723-1805 p. 53 [2].
His birth is recorded on page 27 of the above mentioned source.
Godmother: Elisabeth Gilles from Waldorf
Godfather: Martin Wolff from Schmidtheim
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DNA Connections
It may be possible to confirm family relationships with Martin by comparing test results with other carriers of his Y-chromosome or his mother's mitochondrial DNA.
However, there are no known yDNA or mtDNA test-takers in his direct paternal or maternal line.
It is likely that these autosomal DNA test-takers will share some percentage of DNA with Martin: