"Pa" means the person had begun the naturalization process, but was not yet naturalized. The 1900 Census instructions say "If he was born abroad and has taken no steps toward becoming an American citizen, write "Al" (for alien). If he has declared his intention to become an American citizen and has taken out his "first" papers, write "Pa" (for papers). If he has become a full citizen by taking out second or final papers of naturalization, write "Na" (for naturalized)."
You can see the full instructions at 1900instructions.pdf (census.gov) p. 31.