I believe this is George's mother and not his wife. She was born in 1833 and is listed as George's son's grandmother in 1920. George was born in 1854.
United States Census, 1920," database with images, FamilySearch (https://familysearch.org/ark:/61903/1:1:MNTV-WDB : accessed 14 October 2018), Tal Bryant, Beat 4, Sunflower, Mississippi, United States; citing ED 123, sheet 10A, line 13, family 228, NARA microfilm publication T625 (Washington D.C.: National Archives and Records Administration, 1992), roll 894; FHL microfilm 1,820,894. LIVING WITH GRANDSON (TAL BRYANT WHO IS LISTED AS SON ON THIS PROFILE). BORN IN VIRGINIA.
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It may be possible to confirm family relationships with Ann by comparing test results with other carriers of her mitochondrial DNA.
However, there are no known mtDNA test-takers in her direct maternal line.
It is likely that these autosomal DNA test-takers will share some percentage of DNA with Ann: