It may be that Mary never married.
In Culpepper Co. Deed Book QQ pages 171-172 it is seen that in 1824 Vachel Barnes (presumably the husband of Charity(2) and Methodist trustee along with Benjamin0 agreed to sell personal property to secure two debts (i) to Mary MCDOUGLE for $276 to a Joseph Lewis for $80.
The property to be sold at auction included: 3 bay horses and 1 bay colt, 6 chains, 3 cows and 2 calves, 2 tables, 2 head of sheep, 1 cupboard and furniture, 2 sows with 20 pigs, 3 posts and 1 tea kettle, 30 barrels of corn, 2 ovens, 2 feather beds, bedsteads, 1 skillet and furniture, 1 fodder house, 2 chests
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It may be possible to confirm family relationships with Mary by comparing test results with other carriers of her ancestors' mitochondrial DNA.
However, there are no known mtDNA test-takers in her direct maternal line.
It is likely that these autosomal DNA test-takers will share some percentage of DNA with Mary: